@article {2666,
	title = {Single step Production of graphite from organic Samples for Radiocarbon Measurements},
	journal = {Radiocarbon},
	volume = {61},
	year = {2019},
	month = {Jan-12-2019},
	pages = {1843 - 1854},
	abstract = {We present a new low-cost, high-throughput method for converting many types of organic carbon samples into graphite for radiocarbon (14C) measurements by accelerator mass spectrometry (AMS). The method combines sample combustion and reduction to graphite into a single procedure. In the Single Step method, solid samples are placed directly into Pyrex containing zinc, titanium hydride and iron catalyst. The tube is evacuated, flame sealed, and placed in a muffle furnace for 7 hr. A variety of organic samples have been tested including oxalic acid, sucrose, wood, peat, collagen, humic acid, and contamination swipe samples. The method significantly reduces the time required to produce a graphite sample for 14C measurement, with analytical precision and accuracy approaching that of traditional two-step combustion and hydrogen reduction methods. The details and applicability of the method are presented.},
	keywords = {graphite, radiocarbon, sealed tube graphite, single step graphite},
	issn = {0033-8222},
	doi = {10.1017/RDC.2019.136},
	url = {https://www.cambridge.org/core/product/identifier/S003382221900136X/type/journal_articlehttps://www.cambridge.org/core/services/aop-cambridge-core/content/view/S003382221900136X},
	author = {Elder, K L and Roberts, M L and Walther, T and Xu, L}
}
@article {1835,
	title = {The Passage of the Bomb Radiocarbon Pulse into the Pacific Ocean},
	journal = {Radiocarbon},
	volume = {52},
	year = {2010},
	note = {Sp. Iss. 2696jo
Times Cited:7
Cited References Count:38
},
	month = {2010},
	pages = {1182-1190},
	abstract = {We report and compare radiocarbon observations made on 2 meridional oceanographic sections along 150 degrees W in the South Pacific in 1991 and 2005. The distributions reflect the progressive penetration of nuclear weapons-produced (14)C into the oceanic thermocline. The changes over the 14 yr between occupations are demonstrably large relative to any possible drift in our analytical standardization. The computed difference field based on the gridded data in the upper 1600 m of the section exhibits a significant decrease over time (approaching 40 to 50 parts per thousand in Delta(14)C) in the upper 200-300 m, consistent with the decadal post-bomb decline in atmospheric (14)C levels. A strong positive anomaly (increase with time), centered on the low salinity core of the Antarctic Intermediate Water (AAIW), approaches 50-60 parts per thousand in Delta(14)C, a clear signature of the downstream evolution of the (14)C transient in this water mass. We use this observation to estimate the transit time of AAIW from its "source region" in the southeast South Pacific and to compute the effective reservoir age of this water mass. The 2 sections show small but significant changes in the abyssal (14)C distributions. Between 1991 and 2005, Delta(14)C has increased by 9 parts per thousand below 2000 m north of 55 degrees S. This change is accompanied overall by a modest increase in salinity and dissolved oxygen, as well as a slight decrease in dissolved silica. Such changes are indicative of greater ventilation. Calculation of "phosphate star" also indicates that this may be due to a shift from the Southern Ocean toward North Atlantic Deep Water as the ventilation source of the abyssal South Pacific.},
	keywords = {AMS, antarctic intermediate water, anthropogenic co2, atlantic, c-14 data, carbon, distributions, graphite, south-pacific, tritium},
	isbn = {0033-8222},
	author = {Jenkins, W. J. and Elder, K. L. and McNichol, A. P. and von Reden, K.}
}
@conference {1692,
	title = {Microscale AMS (super <sup>14</sup>) C measurement at NOSAMS},
	volume = {40},
	year = {1998},
	note = {id: 2237; Source type: conferencepapers\&proceedings; Object type: Article; Object type: Conference Paper; Copyright: GeoRef, Copyright 2007, American Geological Institute.; CSAUnique: 1999-044438; AccNum: 1999-044438; ISSN: 0033-8222; CODEN: RACAAT},
	month = {1998},
	pages = {61-75},
	publisher = {University of Arizona, Department of Geosciences, Tucson, AZ, United States (USA)},
	organization = {University of Arizona, Department of Geosciences, Tucson, AZ, United States (USA)},
	address = {United States (USA)},
	abstract = {Techniques for making precise and accurate radiocarbon accelerator mass spectrometry (AMS) measurements on samples containing less than a few hundred micrograms of carbon are being developed at the NOSAMS facility. A detailed examination of all aspects of the sample preparation and data analysis process shows encouraging results. Small quantities of CO (sub 2) are reduced to graphite over cobalt catalyst at an optimal temperature of 605 degrees C. Measured (super 14) C/ (super 12) C ratios of the resulting targets are affected by machine-induced isotopic fractionation, which appears directly related to the decrease in ion current generated by the smaller sample sizes. It is possible to compensate effectively for this fractionation by measuring samples relative to small standards of identical size. Examination of the various potential sources of background (super 14) C contamination indicates that the sample combustion process is the largest contributor, adding ca. 1 mu g of carbon with a less-than-modern (super 14) C concentration.},
	keywords = {03, absolute age, accelerator mass spectroscopy, accuracy, C-14, C-14/C-12, carbon, Carbon dioxide, combustion, data processing, Geochronology, graphite, isotope fractionation, isotopes, mass spectroscopy, mathematical methods, methods, native elements, radioactive isotopes, sample preparation, size, spectroscopy, Stable isotopes},
	doi = {10.1017/S0033822200017902},
	url = {http://hdl.handle.net/10150/653650},
	author = {Pearson, Ann and McNichol, Ann P. and Schneider, Robert J. and von Reden, Karl F. and Zheng, Yan}
}
