@article {2804,
	title = {How Could a Freshwater Swamp Produce a Chemical Signature Characteristic of a Saltmarsh?How Could a Freshwater Swamp Produce a Chemical Signature Characteristic of a Saltmarsh?},
	journal = {ACS Earth and Space Chemistry},
	volume = {2},
	year = {2018},
	month = {Jun-01-2019},
	pages = {9 - 20},
	abstract = {Reduction{\textendash}oxidation (redox) reaction conditions, which are of great importance for the soil chemistry of coastal marshes, can be temporally dynamic. We present a transect of cores from northwest Florida wherein radical postdepositional changes in the redox regime has created atypical geochemical profiles at the bottom of the sedimentary column. The stratigraphy is consistent along the transect, consisting of, from the bottom upward, carbonate bedrock, a gray clay, an organic mud section, a dense clay layer, and an upper organic mud unit representing the current saltwater marsh. However, the geochemical signature of the lower organic mud unit suggests pervasive redox reactions, although the interval has been identified as representing a freshwater marsh, an unlikely environment for such conditions. Analyses indicate that this discrepancy results from postdepositional diagenesis driven by millennial-scale environmental parameters. Rising sea level that led to the deposition of the capping clay layer, created anaerobic conditions in the freshwater swamp interval, and isolated it hydrologically from the rest of the sediment column. The subsequent infiltration of marine water into this organic material led to sulfate reduction, the buildup of H2S and FeS, and anoxic conditions. Continued sulfidation eventually resulted in euxinic conditions, as evidenced by elevated levels of Fe, S, and especially Mo, the diagnostic marker of euxinia. Because this chemical transformation occurred long after the original deposition the geochemical signature does not reflect soil chemistry at the time of deposition and cannot be used to infer syn-depositional environmental conditions, emphasizing the importance of recognizing diagenetic processes in paleoenvironmental studies.},
	keywords = {anoxic, diagenesis, euxinic, florida, Molybdenum, reactions, redox, XRF},
	issn = {2472-3452},
	doi = {10.1021/acsearthspacechem.7b00098},
	url = {https://pubs.acs.org/doi/10.1021/acsearthspacechem.7b00098},
	author = {McCloskey, Terrence A. and Smith, Christopher G. and Liu, Kam-biu and Marot, Marci and Haller, Christian}
}
@article {2056,
	title = {Deglacial sea surface temperatures of the western tropical Pacific: A new look at old coral},
	journal = {Paleoceanography},
	volume = {19},
	year = {2004},
	note = {885czTimes Cited:30
Cited References Count:37
},
	month = {Dec 30},
	abstract = {Using Secondary Ion Mass Spectrometry ( SIMS) ion microprobe techniques, we generated annual Sr/Ca cycles with subweekly resolution from chunks of Porites coral retrieved from a Tahiti barrier reef drill core (149degreesW, 17degreesS), representing the period 13,650 to 13,100 years B.P. The centers of pristine skeletal septa were selectively targeted with a 10 mum diameter ion beam spot, avoiding adjacent pore spaces occupied by secondary aragonite needles. Applying a Sr/Ca-sea surface temperature (SST) calibration equation derived from modern Tahiti Porites having the same low growth rate as the fossil specimens, we obtained SSTs similar to0.5degrees-1.5degreesC cooler during the Bolling-Allerod relative to the present day, with no significant change in seasonality. On the contrary, we estimate that analysis of bulk samples would yield excessively cool Sr/Ca-based SST estimates due to the occupation by secondary aragonite crystals of up to 50\% of the skeletal pore space in the ancient samples. We find that growth rate effects on coral Sr/Ca further depress the apparent mean annual derived SSTs (by >3degreesC) and amplify the apparent seasonality by selectively enhancing wintertime cooling. Our microscale analysis of pristine skeleton and application of an appropriate growth-dependent calibration yield Sr/Ca-derived SSTs that are in good agreement with those derived from Mg/Ca ratios of calcitic foraminifera which indicate a continuous postglacial warming of the western tropical Pacific, in phase with the warming of the tropical Atlantic.},
	keywords = {bolling-allerod, climate-change, coral sr/ca, diagenesis, ion microprobe, last deglaciation, paleotemperature proxy, radiocarbon, record, sea surface temperature, sr/ca, strontium, symbiotic coral, trace-elements, tropical pacific},
	isbn = {0883-8305},
	doi = {10.1029/2004PA001084},
	author = {Cohen, A. L. and Hart, S. R.}
}
